However, PTFE as a dielectric material does have one significant shortcoming, which is its molecular transition at room temperature. This causes the dielectric constant (and therefore the signal's phase) to abruptly shift in a predictable but inconvenient manner, when considering the signal integrity demands of high-resolution radars. This transition phase is known as the "PTFE knee", which is shown in the image below, detailing phase vs. temperature plot.
There are several state-of-the-art manufacturing processes that exist to reduce the impact of this molecular activity by increasing the air density of the PTFE dielectric core. However, the PTFE knee cannot be completely eliminated.
Alternate dielectric materials, such as silicon dioxide, can be used in place of PTFE where the designer requires extreme phase stability over temperature and can afford to sacrifice the flexibility/pliability and insertion loss performance of the connection.
That being said, silicon dioxide cable assemblies are only available as pre-formed semi-rigid assemblies and have a bend radius that is at least twice as large as equivalent diameter PTFE cables. This means that the cost of ownership for them is very high, from procurement to integration. Historically, system designers have had to choose which of these tradeoffs the program can accommodate.